Rachel Leigh Cook got to know Ryan Reynolds from 2001-2002 before he really launched his career. Remember when she was in She's All That? We always thought she was sexy, and that film really proved it! They hit it off so well when they met, he followed her out to the set of her movie and they then spent a year being overly romantic to each other. After their split, Cook found her soulmate shortly after and has been married to Daniel Gillies since 2004. Is Matthew Morrison Sexier Than Ryan Reynolds?